PffBT4T

Varuni Dantanarayana
Conformational and energetic disorder in organic semiconductors reduces charge and exciton transport because of the structural defects, thus reducing the efficiency in devices such as organic photovoltaics and organic light-emitting diodes. The main structural heterogeneity is because of the twisting of the polymer backbone that occurs even in polymers that are mostly crystalline. Here, we explore the relationship between polymer backbone twisting and exciton delocalization by means of transient absorption spectroscopy and density functional theory...
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