De novo synthesis of highly substituted pyridines

Federica Paina
This thesis is divided into three chapters. Chapter 1 provides a brief survey of the methodologies currently available for the de novo synthesis of cyclopentadienes. Particular relevance is given to the more general methods and to the preparation of structurally interesting compounds. Mechanistic details will also be given for interesting or unusual reaction pathways. Chapter 2 presents research findings in the field of the application of the decarboxylative Claisen rearrangement (dCr) reaction to the synthesis...
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