Claisen Rearrangements of Heterocycles

Shu Hui Yow
This thesis is divided into five chapters. Chapter 1 is a review of de-aromatisation processes achieved by sigmatropic rearrangement. It covers the two main types of sigmatropic rearrangements, namely [2,3]- and [3,3]-rearrangement. Chapter 2 introduces the decarboxylative Claisen rearrangement (dCr) reaction and the aim to investigate its viability on more elaborate heterocyclic substrates is discussed. Research efforts into the synthesis of 3-sulfonyl-6-alkenyl-1,4-dioxan-2-ones are detailed. Chapter 3 discusses the extension of this methodology towards N-alkylmorpholinones. The...
This data repository is not currently reporting usage information. For information on how your repository can submit usage information, please see our documentation.